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31.
32.
To investigate influences of gravity on mobility of wheeled rovers for future lunar/planetary exploration missions, model experiments of a soil-wheel system were performed on an aircraft during variable gravity maneuvers. The experimental set-up consists of a single rigid wheel and a soil bed with two kinds of dry sands: lunar soil simulant and Toyoura sand. The experimental results revealed that a lower gravity environment yields higher wheel slippage in variable gravity conditions. In addition to the partial gravity experiments, the same experiments with variable wheel load levels were also performed on ground (1 g conditions). The on-ground experiments produced opposite results to those obtained in the partial gravity experiments, where a lower wheel load yields lower slippage in a constant gravity environment. In low gravity environments, fluidity (flowability) of soil increases due to the confining stress reduction in the soil, while the effect of the wheel load on sinkage decreases. As a result, both of these effects are canceled out, and gravity seemingly has no effect on the wheel sinkage. In the meantime, in addition to the effect of wheel load reduction, the increase of the soil flowability lessens the shear resistance to the wheel rotation, as a result of which the wheel is unable to hold sufficient traction in low gravity environments. This suggests that the mobility of the wheel is governed concurrently by two mechanisms: the bearing characteristics to the wheel load, and the shearing characteristics to the wheel rotation. It appears that, in low gravity, the wheel mobility deteriorates due to the relative decrease in the driving force while the wheel sinkage remains constant. Thus, it can be concluded that the lunar and/or Mars’ gravity environments will be unfavorable in terms of the mobility performance of wheels as compared to the earth’s gravity condition. 相似文献
33.
In order to determine microscopic structures of hydrogenated amorphous silicon (a-Si:H) layers incorporated in a-Si:H-based thin-film solar cells, the spectroscopic ellipsometry (SE) analysis of a-Si:H layers prepared by plasma-enhanced chemical vapor deposition has been performed. In particular, we have characterized the a-Si:H layers by applying a new dielectric function model that allows the evaluation of the SiH2 bond densities in a-Si:H networks. This model is based on our finding that the a-Si:H dielectric functions in the visible/ultraviolet region vary systematically with the formation of SiH2-clustered microvoids. We have applied this model to estimate the SiH2 content in a-Si:H layers fabricated on glass substrates, on which the characterization of the SiH2 bonding is generally difficult. The validity of the SE analysis has been confirmed from the direct characterization of the SiHn local structures using infrared ellipsometry. 相似文献
34.
Masakatsu Sugimoto Kazuhiko Fujiwara Ryuhei Wakita Toshiyuki Kida Araki Masuyama Yohji Nakatsuji 《Supramolecular chemistry》2013,25(2-3):145-151
Abstract Acyclic multidentate ligands consisting of an oligooxyethylene chain (di-, tri-, tetra-, and penta-) and two terminal rigid quinaldate end groups were newly prepared and their complexation properties with alkali metal cations were estimated by the solvent extraction method to indicate a better affinity for K+. Among them, the tetraethylene glycol derivative showed the highest K+ binding on about the same level as 18-crown-6. Their conformations in solution and in the solid state were examined by using 1H- and 13C-NMR spectroscopy and X-ray crystal analyses, respectively. The better binding of K+ in comparison with the corresponding glymes or analogues having the same donor sites was reasonably explained by considering the effective co-ordination of the carbonyl oxygen of the ester groups and the parallel π-stacking interaction between two quinaldate surfaces. 相似文献
35.
Makoto Okawara Takeshi Endo Eisuke Fujiwara Takayoshi Hirose 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(4):441-459
Polymers containing 1,4-dihydronicotinamide (P-NAH) alloxan (P-A), and viologen (P-V2+) moieties were synthesized and characterized. P-NAH reduced various organic substances such as lipoic acid, alloxan, and viologens and also immobilized quinone mediated by alloxan. P-A was reduced to the polymer-bearing alloxan radical and the dialuric acid structure without crosslinks by one- and two-electron reduction, respectively, and P-A also mediated the redox reaction occurring between aqueous and organic (water-immiscible) layers. P-V2+ was converted to the stable viologen radical reversibly by one-electron reduction. Electric potentials and currents on photo-reduction of P-V2+ and catalytic behavior of P-V2+ in the reduction of carbonyl compounds were examined. 相似文献
36.
Yoshimasa Makita Tomofumi Danno Keisuke Ikeda Hsien-Han Lee Taro Abe Kento Sogawa Akihiro Nomoto Shin-ichi Fujiwara Akiya Ogawa 《Tetrahedron letters》2017,58(48):4507-4509
Hemicryptophanes are covalent molecular cages, constructed from a cyclotriveratrylene-based host unit and a functional unit linked by covalent spacers, which have been designed to accommodate endohedral functionalities in the cavity. In this study, the synthesis and characterization of the rigid, biphenyl-linked hemicryptophane 1 were investigated by NMR, ESI-MS, and X-ray crystallography. The structure of the inclusion complex, in which a dichloromethane molecule was constructed encapsulated within 1, was characterized by X-ray crystallography. An endohedral, cobalt(II) hemicryptophane complex 2 was also synthesized and characterized ESI-MS and X-ray crystallography. The X-ray crystal structure of 2 showed that the biphenyl-linked hemicryptophane had three components—a molecule each of chloroform and acetonitrile, and a cobalt(II) ion—within its cavity. 相似文献
37.
Prof. Takanori Suzuki Yuto Sakano Dr. Tomohiro Iwai Dr. Shinichi Iwashita Dr. Youhei Miura Dr. Ryo Katoono Prof. Hidetoshi Kawai Prof. Kenshu Fujiwara Prof. Yasushi Tsuji Prof. Takanori Fukushima 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(1):117-123
When two benzene rings are fused to a tetraaryl‐o‐quinodimethane skeleton, sterically hindered helical molecules 1 acquire a high thermodynamic stability. Because the tetraarylbutadiene subunit contains electron‐donating alkoxy groups, 1 undergo reversible two‐electron oxidation to 2 2+, which can be isolated as deeply colored stable salts. Intramolecular transfer of the point chirality (e.g., sec‐butyl) on the aryl groups to helicity induces a diastereomeric preference in dications 2 b 2+ and 2 c 2+, which represents an efficient method for enhancing circular‐dichroism signals. Thus, those redox pairs can serve as new electrochiroptical response systems. X‐ray analysis of dication 2 2+ revealed π–π stacking interaction of the diarylmethylium moieties, which is also present in solution. The stacking geometry is the key contributor to the chirosolvatochromic response. 相似文献
38.
K Yoshino M Fujiwara A Tanaka S Takahashi Y Nambu A Tomita S Miki T Yamashita Z Wang M Sasaki A Tajima 《Optics letters》2012,37(2):223-225
A high-speed quantum key distribution system was developed with the wavelength-division multiplexing (WDM) technique and dedicated key distillation hardware engines. Two interferometers for encoding and decoding are shared over eight wavelengths to reduce the system's size, cost, and control complexity. The key distillation engines can process a huge amount of data from the WDM channels by using a 1 Mbit block in real time. We demonstrated a three-channel WDM system that simultaneously uses avalanche photodiodes and superconducting single-photon detectors. We achieved 12 h continuous key generation with a secure key rate of 208 kilobits per second through a 45 km field fiber with 14.5 dB loss. 相似文献
39.
A linear algebraic theory called the 'multiple Arnoldi method' is presented and realizes large-scale (order-N) electronic structure calculations with generalized eigenvalue equations. A set of linear equations, in the form of (zS - H)x = b, are solved simultaneously with multiple Krylov subspaces. The method is implemented in a simulation package ELSES (www.elses.jp) with tight-binding-form Hamiltonians. A finite-temperature molecular dynamics simulation is carried out for metallic and insulating materials. A calculation with 10(7) atoms was realized by a workstation. The parallel efficiency is shown up to 1024 CPU cores. 相似文献
40.
Optical path-length matrix method for estimating skin spectrum 总被引:2,自引:0,他引:2
Satoshi Yamamoto Izumi Fujiwara Midori Yamauchi Norimichi Tsumura Keiko Ogawa-Ochiai 《Optical Review》2012,19(6):361-365
In this article, we propose a new method??the optical path-length matrix method (OPLM)??as a faster alternative to the Monte Carlo for multi-layered media (MCML), which is often used to simulate the skin spectrum. Theoretically, peripheral oxygen saturation can be estimated by iterating MCML, but it is not a realistic strategy because it requires huge computation time. The optical path-length matrix is obtained as the probabilistic density histograms of the optical path length in skin using MCML, and once the matrix is obtained, skin spectral reflectance can be calculated by accumulating all combinations of elements in the matrix and by setting an absorption coefficient based on the Beer-Lambert law. The computational time of OPLM was approximately 26,000 times faster than that of MCML. 相似文献